Synthesis and Characterization of Trivalent Al Substituted Zinc Ferrite using Ethylene Diamine (EDA) as Ligand

Authors

  • Soumya Mukherjee Department of Metallurgical Engineering, Kazi NazrulUniversity, PO Kalla More, Asansol, 713340, India

DOI:

https://doi.org/10.30564/omms.v2i2.1863

Abstract

Nano domain Al substituted Zinc ferrite was prepared by chemical route using Ethylene Diamine as ligand. High purity precursors nitrate salts of Zinc, Fe(3+), Al(3+) were utilized along with citric acid which acts as both fuel and complexing agent. Two different molar ratios of Zn(2+):(Fe3+):Al(3+) is 1:1.5:0.5 and 1:1.25:0.75. After ensuring proper mix of the solution Ethylene diamine was added dropwise to form a gel like mass with proper pH control. Before annealing, thermal analysis was carried to determine the crystallization/phase transition zone. Drying was carried in several stages. Initially, gel like mass was obtained after drying at 40°C while pH was about 7. Drying of gel was carried in oil bath at about 90°C and powdered mass obtained was grinded followed by auto combustion at 150°C for 60 minutes before annealing at 150°C, 350°C, 650°C, 950°C for 2 hours to ensure the phase formation. Crystallite size, lattice strain and lattice parameters were studied from XRD analysis.

Keywords:

Al substituted Zinc ferrite, Ethylene Diamine, Thermal analysis, Phase analysis, Strain analysis

References

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How to Cite

Mukherjee, S. (2020). Synthesis and Characterization of Trivalent Al Substituted Zinc Ferrite using Ethylene Diamine (EDA) as Ligand. Non-Metallic Material Science, 2(2), 8–14. https://doi.org/10.30564/omms.v2i2.1863

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