Chemical Mesoscopics Notions in the Explanation of Polymeric Materials Modification Mechanism with Participation of Metal Carbon Mesocomposites

V. I. Kodolov (Basic Research - High Educational Centre of Chemical Physics & Mesoscopics, UD, RAS, Izhevsk, Russia; M.T. Kalashnikov Izhevsk State Technical University, Izhevsk, Russia)
V. V. Kodolova-Chukhontseva (Basic Research - High Educational Centre of Chemical Physics & Mesoscopics, UD, RAS, Izhevsk, Russia; Institute of Macromolecular Compounds, Russian Academy of Sciences, St Petersburg, Russia)
I. N. Shabanova (Basic Research - High Educational Centre of Chemical Physics & Mesoscopics, UD, RAS, Izhevsk, Russia;Udmurt Federal Research Centre, Russian Academy of Sciences, Izhevsk, Russia)
N. S. Terebova (Basic Research - High Educational Centre of Chemical Physics & Mesoscopics, UD, RAS, Izhevsk, Russia;Udmurt Federal Research Centre, Russian Academy of Sciences, Izhevsk, Russia)
Yu. V. Pershin (Basic Research - High Educational Centre of Chemical Physics & Mesoscopics, UD, RAS, Izhevsk, Russia; M.T. Kalashnikov Izhevsk State Technical University, Izhevsk, Russia)
R. V. Mustakimov (Basic Research - High Educational Centre of Chemical Physics & Mesoscopics, UD, RAS, Izhevsk, Russia; M.T. Kalashnikov Izhevsk State Technical University, Izhevsk, Russia)

Article ID: 2587

DOI: https://doi.org/10.30564/opmr.v2i2.2587

Abstract


The paper is dedicated to the consideration of the chemical mesoscopics notions application for the explanation of polymeric materials modification mechanism by the metal carbon mesoscopic composites. The main peculiarities of these nanosized particles are following: a) the presence of unpaired electrons on the carbon cover; b) the structure of carbon cover consists from poly acetylene and carbine fragments; c) the atomic magnetic moment of inner metal is equaled to more than 1,3 μB. The metal carbon mesocomposites activity depends on the medium and conditions influence because of the possible changes of the phase coherency and quantization of negative charges.


Keywords


Chemical mesoscopics;Quantization;Phase coherency;X ray Photoelectron spectra;IR spectra;AFM images;Metal carbon mesocomposites;Modification;Self organization

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References


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