Thermo-oxidative Oligomerization of Aromatic Diamine

Authors

  • B. А. Zaitsev Institute of Macromolecular Compounds, Russian Academy of Sciences, Saint Petersburg, 199004, Russia
  • L. G. Kleptsova Institute of Macromolecular Compounds, Russian Academy of Sciences, Saint Petersburg, 199004, Russia
  • I. D. Shvabskaya Institute of Macromolecular Compounds, Russian Academy of Sciences, Saint Petersburg, 199004, Russia
  • А.E. Bursian Institute of Macromolecular Compounds, Russian Academy of Sciences, Saint Petersburg, 199004, Russia

DOI:

https://doi.org/10.30564/opmr.v3i1.3612

Abstract

Molecular spectroscopy (electronic, FT-IR, NMR), methods of thermal and elemental analysis were used for the first time to describe the process of thermo-oxidative oligomerization of 1,3-bis-(4-aminophenoxy)benzene. Introduction of this monomer into linear and network copolymers makes it possible to improve processability, mechanical strength and heat resistance of materials. The structures of copolymers obtained by thermo-oxidation of the diamine in various thermal regimes were studied. It was demonstrated that during prolonged heating of this diamine in air in the temperature range from 220 to 320°C, oligomeric aromatic diamines were formed; these products contained fragments of benzenoid and quinoid types.

Keywords:

Aromatic diamines, Oxidative oligomerization, Thermal properties, Molecular spectroscopy

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How to Cite

Zaitsev B. А., Kleptsova, L. G., Shvabskaya, I. D., & Bursian А. (2021). Thermo-oxidative Oligomerization of Aromatic Diamine. Organic Polymer Material Research, 3(1), 24–31. https://doi.org/10.30564/opmr.v3i1.3612

Issue

Vol. 3 , Iss. 1 (June 2021)

Article Type

Articles

License

Copyright © 2021 Zaitsev Boris A., Kleptsova Larisa G., Shvabskaya Irina D., Bursian Anna E.

Creative Commons License

This is an open access article under the Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) License.

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